Publications: N-Type
3760864
n-type
apa
50
date
desc
year
1
217
https://yeelab.gatech.edu/wp-content/plugins/zotpress/
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Gregory, S. A., Hanus, R., Atassi, A., Rinehart, J. M., Wooding, J. P., Menon, A. K., Losego, M. D., Snyder, G. J., & Yee, S. K. (2021). Quantifying charge carrier localization in chemically doped semiconducting polymers. Nature Materials. https://doi.org/10.1038/s41563-021-01008-0 Cite
Kurdi, K. A., A. Gregory, S., Jhulki, S., Conte, M., Barlow, S., K. Yee, S., & R. Marder, S. (2020). Electron transport in a sequentially doped naphthalene diimide polymer. Materials Advances, 1(6), 1829–1834. https://doi.org/10.1039/D0MA00406E Cite
Un, H.-I., Gregory, S. A., Mohapatra, S. K., Xiong, M., Longhi, E., Lu, Y., Rigin, S., Jhulki, S., Yang, C.-Y., Timofeeva, T. V., Wang, J.-Y., Yee, S. K., Barlow, S., Marder, S. R., & Pei, J. (2019). Understanding the Effects of Molecular Dopant on n-Type Organic Thermoelectric Properties. Advanced Energy Materials, 9(24), 1900817. https://doi.org/https://doi.org/10.1002/aenm.201900817 Cite
Wolfe, R. M. W., Menon, A. K., Marder, S. R., Reynolds, J. R., & Yee, S. K. (2019). Thermoelectric Performance of n-Type Poly(Ni-tetrathiooxalate) as a Counterpart to Poly(Ni-ethenetetrathiolate): NiTTO versus NiETT. Advanced Electronic Materials, 5(11), 1900066. https://doi.org/https://doi.org/10.1002/aelm.201900066 Cite
Menon, A. K., Wolfe, R. M. W., Kommandur, S., & Yee, S. K. (2019). Progress in Nickel-Coordinated Polymers as Intrinsically Conducting n-Type Thermoelectric Materials. Advanced Electronic Materials, 5(11), 1800884. https://doi.org/https://doi.org/10.1002/aelm.201800884 Cite
Wolfe, R. M. W., Menon, A. K., Fletcher, T. R., Marder, S. R., Reynolds, J. R., & Yee, S. K. (2018). Simultaneous Enhancement in Electrical Conductivity and Thermopower of n-Type NiETT/PVDF Composite Films by Annealing. Advanced Functional Materials, 28(37), 1803275. https://doi.org/https://doi.org/10.1002/adfm.201803275 Cite
Menon, A. K., Wolfe, R. M. W., Marder, S. R., Reynolds, J. R., & Yee, S. K. (2018). Systematic Power Factor Enhancement in n-Type NiETT/PVDF Composite Films. Advanced Functional Materials, 28(29), 1801620. https://doi.org/https://doi.org/10.1002/adfm.201801620 Cite
Menon, A. K., Uzunlar, E., Wolfe, R. M. W., Reynolds, J. R., Marder, S. R., & Yee, S. K. (2017). Metallo-organic n-type thermoelectrics: Emphasizing advances in nickel-ethenetetrathiolates. Journal of Applied Polymer Science, 134(3). https://doi.org/https://doi.org/10.1002/app.44402 Cite
Yee, S. K., Malen, J. A., Majumdar, A., & Segalman, R. A. (2011). Thermoelectricity in Fullerene–Metal Heterojunctions. Nano Letters, 11(10), 4089–4094. https://doi.org/10.1021/nl2014839 Cite